The boom in renewable diesel (RD) production has triggered a race to secure the dozen different bio-feedstocks suitable for refining into diesel fuel. It’s an interesting story that impacts both the oil and agriculture industries, with twists and turns that will take years to play out. In today's RBN blog, we describe the current state of the market and highlight recent happenings in supply chains for two of those increasingly important bio-feedstocks — soybean oil and used cooking oil.
There are two types of biomass-based diesel, commonly called fatty acid methyl ester (FAME) biodiesel and hydrogenated RD. Both are derived from oxygen-containing organic compounds called triglycerides that make up bio-feedstocks like vegetable oils and animal fats. The triglyceride molecule resembles a three-legged barstool. If you detach the legs from the stool, you get three very good diesel fuel molecules, which is why these bio-feedstocks are good raw materials.
The process for making FAME biodiesel fuel detaches the triglyceride’s “legs” by reacting them with methanol, which yields diesel fuel molecules called fatty acid methyl esters, which still contain oxygen atoms. By contrast, the process for making hydrogenated RD detaches the triglyceride’s “legs” by a reaction with hydrogen, yielding oxygen-free fuel molecules identical to those in petroleum-derived diesel. The feedstocks for the two processes are the same, but because FAME biodiesel still has oxygen atoms embedded in its molecules, it must be blended with conventional diesel before being sold as fuel, whereas hydrogenated RD is a pure hydrocarbon just like conventional diesel and can be used directly as a diesel substitute (see Driver’s Seat and Come Clean for more on the process).
The hydrogenation of bio-feedstocks to produce RD is done in oil refineries using the same process used to remove sulfur from conventional diesel and gasoline. Hydrogenation is the most widely used process in petroleum refining — there are more than 1,000 hydrogenation units in refineries around the world. Today, many of them have been redeployed to produce diesel from vegetable oils and animal fats. (In the process, the feedstock is combined with hydrogen gas and the feedstock/gas mixture is pumped through a reactor packed with catalyst. In the reactor, the catalyst promotes the reaction of hydrogen with the feedstock molecules to remove sulfur, nitrogen and oxygen atoms from the feedstock molecules to improve fuel quality and reduce undesirable emissions from burning the fuel. Sulfur is the primary contaminant removed in petroleum refining, while it is almost entirely oxygen which is removed with renewable feedstocks.) U.S. nameplate production capacity of hydrogenated RD has been ramping up at a rapid pace, from 600 million gallons in 2019 (~39 Mb/d) to a scheduled 7.4 billion gallons (~480 Mb/d) in 2024; this year’s growth of 1.4 billion gallons (~91 Mb/d) includes the 680-MMgal/year (~44 Mb/d) Phillips 66 refinery in Rodeo, CA, which has been fully converted from a petroleum refinery to a bio-feedstock refinery to produce hydrogenated RD.
The RD boom — production has risen from 35 Mb/d in 2020 to an expected 227 Mb/d in 2024 and 262 Mb/d by 2026 (see Figure 1 below) — has stressed the upstream markets supplying bio-feedstocks, which come in three broad categories: vegetable oils (like soybean oil, canola oil and corn oil), animal fats (like beef tallow, pork lard and poultry fat), and waste oils (like used cooking oil). Together they are now a 500 Mb/d market as bio-feedstocks.
Figure 1. Annual and Forecast U.S. Renewable Diesel Production. Source: Refined Fuels Analytics
About the song
“Upside Down” was written by Nile Rodgers and Bernard Edwards (Chic) and appears as the first song on side one of Diana Ross’s 11th studio album, diana. Released as the first single from the album, the song went to #1 on the Billboard Hot 100, Disco, and Soul Singles charts. It has been certified Gold by the Recording Industry Association of America. Personnel on the record were: Diana Ross (lead vocals), Bernard Edwards (bass), Nile Rodgers (guitar), Tony Thompson (drums), Andy Barrett (piano), Raymond Jones (keyboards), and Alfa Anderson, Fonzi Thornton, Luci Martin, Michelle Cobbs (backing vocals).
Recorded between December 1979 and March 1980 at the Power Station in New York, diana was produced by Bernard Edwards and Nile Rodgers. Ross and her production team had a falling out over the mixes, and she and Russ Terrana rerecorded her vocals and remixed the album at Electric Lady in New York, and Motown/Hitsville USA studio in Hollywood. The album was released in May 1980 and went to #1 on the Billboard Top R&B/Hip-Hop Albums, and #2 on the Billboard 200 Albums charts. It has been certified Platinum by the RIAA. Three charting singles were released from the LP.
Diana Ross is an American singer, songwriter and actress from Detroit. Ross rose to fame as the lead vocalist for The Supremes, Motown’s most successful act in the ’60s. She left The Supremes in 1970 to embark on a solo career that continues to this day. As a solo artist, she has released 25 studio albums, five live albums, 30 compilation albums, one EP, four soundtrack albums, and 91 singles. As an actress, Ross has starred in five motion pictures and been featured in 35 television shows. She has won seven American Music Awards, one Grammy Award, one Golden Globe Award, and one Tony Award. She has been awarded a Lifetime Achievement Grammy Award, a Presidential Medal of Honor, a Kennedy Center Honor, and has a star on the Hollywood Walk of Fame. She still records and tours, and released her 25th studio album, Thank You, in November 2021.
Comments
From what I've seen, and discussing with engineers converting refineries to RD, it takes a higher pressured hydrotreaters such as what is required for coker or cat cracker feedstock desulfurization, then a hydrocracker to isomerize the biofeed.
I am also hearing that at least one refinery conversion failed to secure feedstock before the conversion and sits idle or limping along at best.
In reply to Process for RD by Kermit Hoffpauir
Thanks for the information about the limping unit. Yes, there are 2 main steps in the RD process, they are oxygen removal and isomerization of linear paraffins to branched paraffins. The isomerization step improves the cold flow properties of the diesel and gives higher diesel yields. You are right about higher pressure units being beneficial. The isomerization step works best when done at relatively high hydrogen partial pressure, with specialized isomerization catalyst, in a separate reactor, on cleaned-up feed. Some producers are putting both catalysts in the same reactor which can be made to work, but with short cycles between catalyst changes and other economic penalties.
In reply to Process for RD by George Hoekstra
Not a huge source but also inedible corn oil extracted from DDGS post ethanol.
Thanks for your comment and for pointing to extraction of corn oil from distiller's dried grains with solubles (DDGS). I had to look that one up. The need for feed should mean opportunity for inventors and entrepreneurs who find better, more economical ways to squeeze triglycerides out of vegetables.